Pd-Catalyzed Allylic C-H Activation to Seven-Membered N,O-Heterocycles
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Royal Society of Chemistry
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Abstract
Pd-catalyzed allylic C-H activation of simple olefins allows an easy entry to seven-membered N,O-heterocycles such as 1,4-benzoxazepines (1,4-BZOs), 1,4-benzodiazepinones (1,4-BZDs) and 1,4-oxazepanes in good to excellent yields. Straightforward derivatizations of the olefinated 1,4-BZO shows the synthetic utility of this methodology.
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Velasco-Rubio, A., Varela, J. A., Saá, C. (2021). Pd-Catalyzed Allylic C-H Activation to Seven-Membered N,O-Heterocycles. Chem. Commun., 57, 83, 10915-10918.
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https://doi.org/10.1039/D1CC04056ASponsors
We acknowledge financial support from MINECO (project CTQ2017-87939R and ORFEO-CINQA network RED2018-102387-T), the Xunta de Galicia (project ED431C 2018/04 and Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03) and the European Union (European Regional Development Fund –
RDF). A.V.-R. thanks Xunta de Galicia for a predoctoral fellowship (ED481A-2018/34, 2018-2021)
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© The Royal Society of Chemistry 2021. This article may be used for non-commercial purposes in accordance with The Royal Society of Chemistry Terms and Conditions for self-archiving