Pd-Catalyzed Allylic C-H Activation to Seven-Membered N,O-Heterocycles

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorVelasco Rubio, Álvaro
dc.contributor.authorVarela Carrete, Jesús Ángel
dc.contributor.authorSaá Rodríguez, Carlos
dc.date.accessioned2021-10-29T11:50:52Z
dc.date.available2022-09-22T01:00:12Z
dc.date.issued2021
dc.description.abstractPd-catalyzed allylic C-H activation of simple olefins allows an easy entry to seven-membered N,O-heterocycles such as 1,4-benzoxazepines (1,4-BZOs), 1,4-benzodiazepinones (1,4-BZDs) and 1,4-oxazepanes in good to excellent yields. Straightforward derivatizations of the olefinated 1,4-BZO shows the synthetic utility of this methodology.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipWe acknowledge financial support from MINECO (project CTQ2017-87939R and ORFEO-CINQA network RED2018-102387-T), the Xunta de Galicia (project ED431C 2018/04 and Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03) and the European Union (European Regional Development Fund – RDF). A.V.-R. thanks Xunta de Galicia for a predoctoral fellowship (ED481A-2018/34, 2018-2021)gl
dc.identifier.citationVelasco-Rubio, A., Varela, J. A., Saá, C. (2021). Pd-Catalyzed Allylic C-H Activation to Seven-Membered N,O-Heterocycles. Chem. Commun., 57, 83, 10915-10918.gl
dc.identifier.doi10.1039/D1CC04056A
dc.identifier.essn1364-548X
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/10347/27041
dc.language.isoenggl
dc.publisherRoyal Society of Chemistrygl
dc.relation.publisherversionhttps://doi.org/10.1039/D1CC04056Agl
dc.rights© The Royal Society of Chemistry 2021. This article may be used for non-commercial purposes in accordance with The Royal Society of Chemistry Terms and Conditions for self-archivinggl
dc.rights.accessRightsopen accessgl
dc.subject1,4-Benzodiazepinonesgl
dc.subject1,4-Benzoxazepinesgl
dc.subject1,4-Oxazepanesgl
dc.subjectC-H Activationgl
dc.subjectN,O-Heterocyclesgl
dc.subjectPalladiumgl
dc.titlePd-Catalyzed Allylic C-H Activation to Seven-Membered N,O-Heterocyclesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublicatione9be05f9-b5a3-405c-aaf6-4e32700dd21d
relation.isAuthorOfPublication2c024eb2-7698-4785-bd0c-518f70068330
relation.isAuthorOfPublication.latestForDiscoverye9be05f9-b5a3-405c-aaf6-4e32700dd21d

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