Unprecedent isolation of a mixture of conformational and linkage isomers in a thiosemicarbazone cobalt mesocate
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Abstract
A cobalt(II) thiosemicarbazonate mesocate has been structurally characterized as an unexpected mixture of conformational and linkage isomers. Moreover, we have shown that the absence of a nitrogen atom in the spacer of the helicand ligand H2La, enables the assembly of an achiral mesohelical complex in the case of Co(II) ions.
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This document is the accepted manuscript version of a published work that was accepted for publication in Inorganic Chemistry © American Chemical Society 2009, after peer review. To access the final edited and published work see https://doi.org/10.1021/ic901657z
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Pedrido, R., Romero, M. J., González-Noya, A. M., Bermejo, M. R., Martínez-Calvo, M. and Zaragoza, G. (2009 ). "Inorganic Chemistry", 48(23), 10862-10864
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© 2009 American Chemical Society. This article may be used for non-commercial purposes in accordance with the American Chemical Society and conditions for Self-Archived versions.