Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy

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URI: http://hdl.handle.net/10347/25870
ISBN: 978-3-03842-145-0
DOI: 10.3390/ecsoc-19-d004

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2015

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Abstract

The curing reaction of a system consisting of a diglycidyl ether of bisphenol-A (n= 0) and ZnTPyP (Zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphyrin) was studied by Fourier Transform infrared spectroscopy (FTIR). A semi-empirical quantum chemistry program (MOPAC) was used to corroborate the experimental data. The tertiary amine ZnTPyP not only initiates the reaction but also reacts with the resin forming pyridone. This study demonstrates that macrocycles can be used as cross-linking agents for curing epoxy resins and that when metallomacrocycles are used, metal ions can be introduced into the network structure

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The 19th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistry

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FTIR| Porphyrins| Epoxy resins| Tertiary amines

Bibliographic citation

Vázquez Barreiro, E.C., Jover Ramos, A., Fraga López, F.J., Vázquez Tato, J. & Seijas, J.A. (2015). Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-19: The 19Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2015. MDPI. doi: 10.3390/ecsoc-19-d004

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