RT Book,_Section
T1 Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy
A1 Vázquez Barreiro, Eva Carolina
A1 Jover Ramos, Aida
A1 Fraga López, Francisco
A1 Vázquez Tato, José
A1 Seijas Vázquez, Julio Antonio
K1 FTIR
K1 Porphyrins
K1 Epoxy resins
K1 Tertiary amines
AB The curing reaction of a system consisting of a diglycidyl ether of bisphenol-A (n= 0) and ZnTPyP (Zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphyrin) was studied by Fourier Transform infrared spectroscopy (FTIR). A semi-empirical quantum chemistry program (MOPAC) was used to corroborate the experimental data. The tertiary amine ZnTPyP not only initiates the reaction but also reacts with the resin forming pyridone. This study demonstrates that macrocycles can be used as cross-linking agents for curing epoxy resins and that when metallomacrocycles are used, metal ions can be introduced into the network structure
PB MDPI
SN 978-3-03842-145-0
YR 2015
FD 2015
LK http://hdl.handle.net/10347/25870
UL http://hdl.handle.net/10347/25870
LA eng
NO Vázquez Barreiro, E.C., Jover Ramos, A., Fraga López, F.J., Vázquez Tato, J. & Seijas, J.A. (2015). Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-19: The 19Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2015. MDPI. doi: 10.3390/ecsoc-19-d004
NO The 19th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistry
DS Minerva
RD 26 abr 2026