Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Física Aplicadagl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Físicagl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorVázquez Barreiro, Eva Carolina
dc.contributor.authorJover Ramos, Aida
dc.contributor.authorFraga López, Francisco
dc.contributor.authorVázquez Tato, José
dc.contributor.authorSeijas Vázquez, Julio Antonio
dc.date.accessioned2021-04-13T11:12:48Z
dc.date.available2021-04-13T11:12:48Z
dc.date.issued2015
dc.descriptionThe 19th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistrygl
dc.description.abstractThe curing reaction of a system consisting of a diglycidyl ether of bisphenol-A (n= 0) and ZnTPyP (Zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphyrin) was studied by Fourier Transform infrared spectroscopy (FTIR). A semi-empirical quantum chemistry program (MOPAC) was used to corroborate the experimental data. The tertiary amine ZnTPyP not only initiates the reaction but also reacts with the resin forming pyridone. This study demonstrates that macrocycles can be used as cross-linking agents for curing epoxy resins and that when metallomacrocycles are used, metal ions can be introduced into the network structuregl
dc.identifier.citationVázquez Barreiro, E.C., Jover Ramos, A., Fraga López, F.J., Vázquez Tato, J. & Seijas, J.A. (2015). Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-19: The 19Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2015. MDPI. doi: 10.3390/ecsoc-19-d004gl
dc.identifier.doi10.3390/ecsoc-19-d004
dc.identifier.isbn978-3-03842-145-0
dc.identifier.urihttp://hdl.handle.net/10347/25870
dc.language.isoenggl
dc.publisherMDPIgl
dc.relation.ispartofseriesElectronic Conference on Synthetic Organic Chemistry;19
dc.relation.publisherversionhttps://doi.org/10.3390/ecsoc-19-d004gl
dc.rights© 2016 by MDPI, Basel, Switzerland. Open Accessgl
dc.rights.accessRightsopen accessgl
dc.subjectFTIRgl
dc.subjectPorphyrinsgl
dc.subjectEpoxy resinsgl
dc.subjectTertiary aminesgl
dc.titleStudy of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopygl
dc.typebook partgl
dspace.entity.typePublication
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relation.isAuthorOfPublication.latestForDiscovery4fca9fe8-5893-4006-8a8b-31928d178951

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