Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánicaes_ES
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicaes_ES
dc.contributor.authorFernández-Fariña, Sandra
dc.contributor.authorGonzález Barcia, Luis
dc.contributor.authorRomero Castro, María José
dc.contributor.authorGarcía Tojal, Javier
dc.contributor.authorManeiro Maneiro, Marcelino
dc.contributor.authorSeco, José M.
dc.contributor.authorZaragoza Vérez, Guillermo
dc.contributor.authorMartínez-Calvo, Miguel
dc.contributor.authorPedrido Castiñeiras, Rosa
dc.contributor.authorGonzález Noya, Ana María
dc.date.accessioned2024-02-06T07:52:02Z
dc.date.available2024-02-06T07:52:02Z
dc.date.issued2021-12-06
dc.description.abstractWe present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reactiones_ES
dc.description.peerreviewedSIes_ES
dc.description.sponsorshipThe research leading to these results has received funding from the following FEDER cofunded-grants: from Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia, 2017 GRC GI-1682 (ED431C 2017/01), 2018 GRC GI-1584 (ED431C 2018/13), MetalBIO Network (ED431D 2017/ 01), Ministerio de Ciencia, Innovación y Universidades, METALBIO (CTQ2017-90802-REDT) and MultiMetDrugs (RED2018-102471-T). Inorg.es_ES
dc.identifier.citationFernández-Fariña, S., González-Barcia, L. M., Romero, M. J., García-Tojal, J., Maneiro, M., Seco, J. M., ... & Pedrido, R. (2022). Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process. Inorganic Chemistry Frontiers, 9(3), 531-536.es_ES
dc.identifier.doi10.1039/D1QI01308D
dc.identifier.essn2052-1553
dc.identifier.urihttp://hdl.handle.net/10347/32379
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relation.publisherversionhttps://doi.org/10.1039/D1QI01308Des_ES
dc.rights© the Partner Organisations 2022es_ES
dc.rights.accessRightsopen accesses_ES
dc.subjectSilveres_ES
dc.subjectCluster helicatees_ES
dc.subjectDesulfurization processes_ES
dc.subjectBisthiosemicarbazonees_ES
dc.subject.classification2303 Química inorgánicaes_ES
dc.titleConversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization processes_ES
dc.typejournal articlees_ES
dc.type.hasVersionAMes_ES
dspace.entity.typePublication
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relation.isAuthorOfPublication.latestForDiscovery39511480-7092-452e-9371-29aeefcb1f81

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