Rhodium(III)-Catalyzed Intramolecular Annulations of Acrylic and Benzoic Acids to Alkynes
| dc.contributor.affiliation | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares | gl |
| dc.contributor.affiliation | Universidade de Santiago de Compostela. Departamento de Química Orgánica | gl |
| dc.contributor.author | Fernández Fernández, David | |
| dc.contributor.author | Casanova González, Noelia | |
| dc.contributor.author | Mascareñas Cid, José Luis | |
| dc.contributor.author | Gulías Costa, Moisés | |
| dc.date.accessioned | 2019-04-08T07:06:39Z | |
| dc.date.available | 2019-04-08T07:06:39Z | |
| dc.date.issued | 2019 | |
| dc.description.abstract | Rh(III) catalysts can promote a formal (4 + 2) intramolecular oxidative annulation between acrylic or benzoic acid derivatives and alkynes. The reaction, which involves a C–H activation process, allows for a rapid assembly of appealing bicyclic pyran-2-ones and tricyclic isocoumarin derivatives in moderate to good yields. The α-pyrone moiety of the products provides for further manipulations to obtain relatively complex cyclic skeletons in a very simple manner | gl |
| dc.description.peerreviewed | SI | gl |
| dc.description.sponsorship | This work has received financial support from Spanish grants (SAF2016-76689-R, CTQ2016-77047-P, and FPI fellowship to D.F.F.), the Consellería de Cultura, Educación e Ordenación Universitaria (ED431C 2017/19, 2015-CP082, and Centro Singular de Investigación de Galicia acreditación 2016-2019, ED431G/09), the European Regional Development Fund (ERDF), and the European Research Council (Advanced Grant no. 340055). The orfeo-cinqa network CTQ2016-81797-REDC is also kindly acknowledged | gl |
| dc.identifier.citation | F. Fernández, D., Casanova, N., Mascareñas, J., & Gulías, M. (2019). Rhodium(III)-Catalyzed Intramolecular Annulations of Acrylic and Benzoic Acids to Alkynes. ACS Omega, 4(4), 6257-6263. doi: 10.1021/acsomega.9b00022 | gl |
| dc.identifier.doi | 10.1021/acsomega.9b00022 | |
| dc.identifier.essn | 2470-1343 | |
| dc.identifier.uri | http://hdl.handle.net/10347/18551 | |
| dc.language.iso | eng | gl |
| dc.publisher | American Chemical Society | gl |
| dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/340055 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-81797/ES | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SAF2016-76689-R/ES | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-81797-REDC/ES | |
| dc.relation.publisherversion | https://doi.org/10.1021/acsomega.9b00022 | gl |
| dc.rights | ACS AuthorChoice - This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes | gl |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | |
| dc.rights.accessRights | open access | gl |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.title | Rhodium(III)-Catalyzed Intramolecular Annulations of Acrylic and Benzoic Acids to Alkynes | gl |
| dc.type | journal article | gl |
| dc.type.hasVersion | VoR | gl |
| dspace.entity.type | Publication | |
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