Methyl 2-diphenylphosphoryloxy-2-azabicyclo[2.2.1]hept-5-ene-3-exocarboxylate

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorSousa, Carlos A.D.
dc.contributor.authorVale, M. Luísa C.
dc.contributor.authorRodríguez Borges, José E.
dc.contributor.authorGarcía Mera, Xerardo
dc.date.accessioned2020-09-29T12:42:46Z
dc.date.available2020-09-29T12:42:46Z
dc.date.issued2009
dc.description.abstractIn the title compound, C20H20NO4P, the dihedral angle between the phenyl rings is 68.52 (7) . In the crystal structure, the molecules are linked by a weak C—H(arene) interaction along [010] involving the phenyl CH group and the phenyl rings. There are no further significant intermolecular interactionsgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipThis work was supported by the Centro de Investigaçao em Química of the University of Porto. The X-ray data were collected at the Unidade de Raios X, RIAIDT, University of Santiago de Compostela. The authors thank Antonio L. Llamas-Saiz for his help and the Fundaçao para a Ciência e Tecnologia (FCT) and Xunta de Galicia for financial support (grants POCTI/QUI/44471/2002 and 07CSA008203-PR, respectively). CADS thanks the FCT for grant No. SFRH/BD/ 31526/2006gl
dc.identifier.citationC. A. D. Sousa, M. L. C. Vale, J. E. Rodríguez-Borges and X. Garcia-Mera. (2009).Methyl 2-diphenyl­phosphor­yloxy-2-aza­bicyclo­[2.2.1]hept-5-ene-3-exo-carboxyl­ate. " Acta Crystallographica Section E", E65, o188gl
dc.identifier.doi10.1107/S160053680804292X
dc.identifier.essn1600-5368
dc.identifier.issn2056-9890
dc.identifier.urihttp://hdl.handle.net/10347/23315
dc.language.isoenggl
dc.publisherInternational Union of Crystallographygl
dc.relation.publisherversionhttps://doi.org/10.1107/S160053680804292Xgl
dc.rights© 2009 The author(s). This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are citedgl
dc.rights.accessRightsopen accessgl
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectSingle-crystal X-ray studygl
dc.subjectT = 100 Kgl
dc.subjectMean (C–C) = 0.002 A˚gl
dc.subjectR factor = 0.035gl
dc.subjectwR factor = 0.091gl
dc.subjectData-to-parameter ratio = 15.8gl
dc.titleMethyl 2-diphenylphosphoryloxy-2-azabicyclo[2.2.1]hept-5-ene-3-exocarboxylategl
dc.typejournal articlegl
dc.type.hasVersionVoRgl
dspace.entity.typePublication
relation.isAuthorOfPublicationf96bea62-c3ca-4b3b-8fb4-1d6a46b4a7c3
relation.isAuthorOfPublication.latestForDiscoveryf96bea62-c3ca-4b3b-8fb4-1d6a46b4a7c3

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