Methyl 2-diphenylphosphoryloxy-2-azabicyclo[2.2.1]hept-5-ene-3-exocarboxylate

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2009_actacryst_sousa_methyl2diphenylphosphoryloxy.pdf (359.04 KB)
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URI: http://hdl.handle.net/10347/23315
ISSN: 2056-9890
E-ISSN: 1600-5368
DOI: 10.1107/S160053680804292X

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2009

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International Union of Crystallography
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Abstract

In the title compound, C20H20NO4P, the dihedral angle between the phenyl rings is 68.52 (7) . In the crystal structure, the molecules are linked by a weak C—H(arene) interaction along [010] involving the phenyl CH group and the phenyl rings. There are no further significant intermolecular interactions

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Single-crystal X-ray study| T = 100 K| Mean (C–C) = 0.002 A˚| R factor = 0.035| wR factor = 0.091| Data-to-parameter ratio = 15.8

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C. A. D. Sousa, M. L. C. Vale, J. E. Rodríguez-Borges and X. Garcia-Mera. (2009).Methyl 2-diphenyl­phosphor­yloxy-2-aza­bicyclo­[2.2.1]hept-5-ene-3-exo-carboxyl­ate. " Acta Crystallographica Section E", E65, o188

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This work was supported by the Centro de Investigaçao em Química of the University of Porto. The X-ray data were collected at the Unidade de Raios X, RIAIDT, University of Santiago de Compostela. The authors thank Antonio L. Llamas-Saiz for his help and the Fundaçao para a Ciência e Tecnologia (FCT) and Xunta de Galicia for financial support (grants POCTI/QUI/44471/2002 and 07CSA008203-PR, respectively). CADS thanks the FCT for grant No. SFRH/BD/ 31526/2006

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© 2009 The author(s). This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited

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