Palladium-Catalyzed Conjugate Addition of Terminal Alkynes to Enones

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorVillarino Palmaz, Lara
dc.contributor.authorGarcía Fandiño, Rebeca
dc.contributor.authorLópez García, Fernando
dc.contributor.authorMascareñas Cid, José Luis
dc.date.accessioned2019-03-27T13:11:45Z
dc.date.available2019-03-27T13:11:45Z
dc.date.issued2012
dc.descriptionThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Chemical Biology, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see: https://pubs.acs.org/doi/10.1021/ol300988ngl
dc.description.abstractA practical protocol for the hydroalkynylation of enones using Pd catalysis is reported. The reaction proceeds efficiently with a variety of alkynes as well as with several cyclic and acyclic enones, providing synthetically relevant β-alkynyl ketones in good to excellent yieldsgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipThis work was supported by the Spanish MINECO [SAF2007-61015, SAF2010-20822-C02, Consolider Ingenio 2010 CSD2007-00006], the ERDF and the Xunta de Galicia INCITE09209084PR, GRC2010/12. L.V. and R.G.-F. thank the Spanish MEC and MINECO for an FPU fellowship and a Juan de la Cierva contract, respectivelygl
dc.identifier.citationVillarino, L., García-Fandiño, R., López, F., & Mascareñas, J. (2012). Palladium-Catalyzed Conjugate Addition of Terminal Alkynes to Enones. Org. Lett., 14, 12, 2996-2999. DOI: 10.1021/ol300988ngl
dc.identifier.doi10.1021/ol300988n
dc.identifier.essn1523-7052
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10347/18477
dc.language.isoenggl
dc.publisherAmerican Chemical Societygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/SAF2010-20822-C02/ES/DISEÑO Y DESARROLLO DE PROCESOS ENANTIOSELECTIVOS CATALIZADOS POR METALES DE TRANSICION PARA LA OBTENCION DE ESTRUCTURAS POLICICLICAS BIOLOGICAMENTE RELAVANTES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC/Plan Nacional de I+D+i 2004-2007/CSD2007-00006/ES/Desarrollo de entidades organometálicas para reacciones de funcionalización selectiva en moléculas orgánicas
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC/Plan Nacional de I+D+i 2004-2007/SAF2007-61015/ES/HERRAMIENTAS Y ESTRATEGIAS MOLECULARES PARA EL ESTUDIO Y MODIFICACION DE PROCESOS BIOLOGICOS DE RELEVANCIA BIOMEDICA
dc.relation.publisherversionhttps://doi.org/10.1021/ol300988ngl
dc.rights© 2012 American Chemical Societygl
dc.rights.accessRightsopen accessgl
dc.titlePalladium-Catalyzed Conjugate Addition of Terminal Alkynes to Enonesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication08e9d7b3-78e4-4dd1-9f4b-4d65a675c331
relation.isAuthorOfPublication7207f196-ba01-47c3-a5a7-dac268e007d3
relation.isAuthorOfPublication5ae222c9-f626-432b-aac5-da78c06ed64f
relation.isAuthorOfPublication.latestForDiscovery08e9d7b3-78e4-4dd1-9f4b-4d65a675c331

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