Velasco Rubio, ÁlvaroVarela Carrete, Jesús ÁngelSaá Rodríguez, Carlos2021-10-292022-09-222021Velasco-Rubio, A., Varela, J. A., Saá, C. (2021). Pd-Catalyzed Allylic C-H Activation to Seven-Membered N,O-Heterocycles. Chem. Commun., 57, 83, 10915-10918.1359-7345http://hdl.handle.net/10347/27041Pd-catalyzed allylic C-H activation of simple olefins allows an easy entry to seven-membered N,O-heterocycles such as 1,4-benzoxazepines (1,4-BZOs), 1,4-benzodiazepinones (1,4-BZDs) and 1,4-oxazepanes in good to excellent yields. Straightforward derivatizations of the olefinated 1,4-BZO shows the synthetic utility of this methodology.eng© The Royal Society of Chemistry 2021. This article may be used for non-commercial purposes in accordance with The Royal Society of Chemistry Terms and Conditions for self-archiving1,4-Benzodiazepinones1,4-Benzoxazepines1,4-OxazepanesC-H ActivationN,O-HeterocyclesPalladiumjournal article10.1039/D1CC04056A1364-548Xopen access