García Río, LuisFrancisco, Vítor Manuel dos SantosFacultade de Química. Departamento de Química Física. Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares2014-02-062014-02-062014-02-06http://hdl.handle.net/10347/9837This thesis describes the host-guest chemistry between different macrocycles with various guests in aqueous solution. The focus of this thesis is the influence of ionic molecules, which are typically neglected, in the binding affinities and thermodynamic parameters of the complexation of guests by macrocycles. In this sense, an extensively studied macrocycle and its counterion, often a inorganic cation, was selected as a host.engEsta obra atópase baixo unha licenza internacional Creative Commons BY-NC-ND 4.0. Calquera forma de reprodución, distribución, comunicación pública ou transformación desta obra non incluída na licenza Creative Commons BY-NC-ND 4.0 só pode ser realizada coa autorización expresa dos titulares, salvo excepción prevista pola lei. Pode acceder Vde. ao texto completo da licenza nesta ligazón: https://creativecommons.org/licenses/by-nc-nd/4.0/deed.glhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.glSupramolecular chemistryMacrocyclesHost‒guest complexMaterias::Investigación::23 Química:: 2307 Química físicaThermodynamic and structural studies on the interaction of guests with macrocyclesdoctoral thesisopen access