García Deibe, Ana MaríaPortela GarcíaPortela García, CristinaFondo Busto, María MatildeSanmartín Matalobos, Jesús2021-04-142021-04-142015García-Deibe, A., Portela-García, C., Fondo, M. & Sanmartín-Matalobos, J. (2015). H-bonded polymerisation of alternate ∆ and Λ metallohelicates. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-18: The 18Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2014. MDPI. doi: 10.3390/ecsoc-18-d011978-3-906980-55-3http://hdl.handle.net/10347/25978The 18th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistryhe neutral cadmium(II) complex Cd(HL)2 (H2L = 2-[(1H-imidazol-2-yl)methyleneamino]phenol) is chiral and it can be considered as a simple metallohelicate, with its corresponding Δ and Λ enantiomers. In the solid state, its helixes are hierarchically assembled as a linear polymer, via mutual N-H···O interactions between each two alternating enantiomers, and which also are π-π stacked, so this polymer is based on a by a dimeric repeat unit {Δ,Λ-[Cd(HL)2]2}eng© 2015 by MDPI, Basel, Switzerland. Open AccessChiralityH-bondPolymerMetallohelicateSelf-assemblybook part10.3390/ecsoc-18-d011open access