Frieiro Gomis, PabloLucio Martínez, FátimaMunín Cruz, PaulaOrtigueira Amor, Juan ManuelPereira Lorenzo, María TeresaPolo Ces, PaulaVázquez García, DignaVila Abad, José Manuel2025-01-302025-01-302018-02-19Frieiro-Gomis, P., Lucio-Martínez, F., Munín-Cruz, P., M. Ortigueira, J., Teresa Pereira, M., Polo-Ces, P., Vázquez-García, D., & M. Vila, J. (2018). The chelate-to-bridging shift of phosphane dipalladacycles: Convenient synthesis of double A-frame tetranuclear complexes. “Chemical Communications”, 54(21), 2662-2665. https://doi.org/10.1039/C8CC01046C1359-7345https://hdl.handle.net/10347/39367Palladacycles of the type [Pd2(Ph2PCH2PPh2-P,P)2(C,N:C,N)] (C,N:C,N = bis(N-2,3,4-trimethoxybenzylidene)-4,4′-sulfonyldianiline or -4,4′-oxydianiline) can undergo a spontaneous slow chelate-to-bridging diphosphane coordination shift in solution. Following this strategy a tailor-made synthetic procedure was devised that culminates in isolation of double A-frame tetranuclear palladium complexes.eng© The Royal Society of Chemistry, 2018http://creativecommons.org/licenses/by-nc-nd/4.0/Phosphane dipalladacyclesChelate-to-bridgingTetranuclear complexes2303 Química inorgánicajournal article10.1039/C8CC01046C1364-548Xopen access