Díaz-Marta, Antonio S.Yáñez, SusanaLasorsa, ElianaPacheco, PatriciaTubío, Carmen R.Rivas Rey, JoséPiñeiro Redondo, YolandaGonzález Gómez, Manuel AntonioAmorín López, ManuelGuitián Rivera, FranciscoCoelho Cotón, Alberto José2025-01-212025-01-212020-02-061867-3880https://hdl.handle.net/10347/38814For this work, an integrated system composed of a polypropylene reactor and a palladium on silica monolithic catalyst was designed and manufactured by 3D-printing. These devices are able to perform solution phase chemistry in a robotic orbital shaker. The capped reactor was obtained in its entirety by 3D-printing, using polypropylene and fused deposition modeling. The monolithic catalyst was also obtained by 3D-printing -robocasting- of a silica support, sintering and subsequent palladium deposition through the wet impregnation method. The catalytic efficiency in Sonogashira or Suzuki reactions as well as the recyclability of the entire system – catalyst+reactor – were studied. The strong electrostatic adsorption (SEA) of the palladium on sintered silica and the reduced mechanical stress produced by the convenient adjustment of the catalyst into the polypropylene reactor makes the catalytic system reusable without significant loss of catalytic activity.engUso sujeto a las condiciones de la editorial Wiley-VCH3D-printingMonolithic CatalystPalladiumSonogashiraStrong Electrostatic AdsorptionSuzuki2306 Química orgánicajournal article10.1002/cctc.201902143restricted access