Chaves Pouso, AndreaRivera Chao, EvaFañanás-Mastral, Martín2020-10-092021-09-082020Chaves-Pouso, A., Rivera-Chao, E., & Fañanás-Mastral, M. (2020). Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes. Chemical Communications. https://doi.org/10.1039/d0cc04018ehttp://hdl.handle.net/10347/23373A copper-catalyzed protoboration of borylated dendralenes is reported. The method employs an NHC–Cu catalyst and provides access to 1,4-addition products with excellent levels of chemo-, regio- and stereoselectivity. The resulting diene bis(boronates) are oxidized to the corresponding diene diols which are synthetically versatile building blocks.eng© The Royal Society of Chemistry 2020. This article may be used for non- commercial purposes in accordance with RSC Terms and Conditions for Use of Self-Archived Versionsjournal article10.1039/D0CC04018E1364-548Xopen access