Lucio Martínez, FátimaAdrio, Luis A.Polo Ces, PaulaOrtigueira Amor, Juan ManuelFernández, Jesús J.Adams, HarryPereira Lorenzo, María TeresaVila Abad, José Manuel2025-01-312025-01-312016Lucio-Martínez, F., Adrio, L. A., Polo-Ces, P., Ortigueira, J. M., Fernández, J. J., Adams, H., Pereira, M. T., Vila, J. M. (2016). Palladacycle catalysis: an innovation to the Suzuki–Miyaura cross-coupling reaction." Dalton Transactions", vol.45, 17598-17601 https://doi.org/10.1039/c6dt03542f1477-9226https://hdl.handle.net/10347/39425Herein we report a Suzuki−Miyaura type cross−coupling between an aryl halide and a functionalized boronic acid palladacycle in the absence of an external catalyst. This reaction is an unprecedented case of catalysis in palladium metallacycle chemistryeng© The Royal Society of Chemistry 2016http://creativecommons.org/licenses/by-nc-nd/4.0/CyclometallationCatalysisCross-coupling230316 Mecanismos de las reacciones inorgánicasPalladacycle catalysis: an innovation to the Suzuki−Miyaura cross−coupling reactionjournal article10.1039/C6DT03542F1477-9234restricted access