Coronado, EugenioGalán Mascarós, José R.Giménez López, María del CarmenAlmeida, ManuelWaerenborgh, João Carlos2024-02-052024-02-052006Coronado, E., Galán Mascarós, J.R., Giménez-López, M.C., Almeida, M., Waerenborgh, J.C. (2006). Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets. "Polyhedron". Vol.26, n. 9–11, 1838-18440277-5387http://hdl.handle.net/10347/32319We present the synthesis and structural characterization of the salt [Fe(bpp)2][MnCr(ox)3]2 · bpp · CH3OH. It crystallizes in the monoclinic space group. This material contains an anionic [MnCr(ox)3]− 3D 10-gon ferromagnetic network, that orders below 3.0 K. The channels created by this architecture are filled by the spin crossover cations [Fe(bpp)2]2+ (bpp = 2,6(bispyrazol-3-yl)pyridine), free ligand and solvent molecules. No spin transition has been observed at ambient pressure.engCC BY-NC-ND 4.0http://creativecommons.org/licenses/by-nc-nd/4.0/Coordination chemistryMolecular materialsSpin crossoverMagnetic propertiesMössbauer spectroscopy230307 Compuestos de coordinación220208 Magnetismojournal article10.1016/j.poly.2006.09.0641873-3719open access