RT Journal Article T1 Orbital, charge, and spin couplings in Ru 25+O9 dimers of Ba3CoRu2O9 A1 Zhou, Haidong A1 Kiswandhi, Andhika A1 Barlas, Yafis A1 Brooks, James A1 Siegrist, Theo Max A1 Li, G. A1 Balicas, Luis A1 Cheng, J. G. A1 Rivadulla Fernández, José Francisco AB e magnetic, transport, and structural properties of cold-pressed Ba3CoRu2O9 show (i) an antiferromagnetic transition, (ii) a semiconductor-semiconductor electronic transition where the resistivity is dominated by the electron hopping between the Ru25+O9 dimers with itinerant Ru electrons at high temperatures, and (iii) a hexagonal to orthorhombic structural phase transition. All three transitions occur at 93 K and are related to the Ru5+ ions in the Ru2O9 dimers. The Ru-O bond distortion below 93 K further indicates a possible orbital ordering for Ru5+ ions in isolated Ru2O9 dimers, which accounts for the strong orbital, charge, and spin couplings PB APS Physics SN 2469-9950 YR 2012 FD 2012 LK http://hdl.handle.net/10347/17038 UL http://hdl.handle.net/10347/17038 LA eng NO Zhou, H., Kiswandhi, A., Barlas, Y., Brooks, J., Siegrist, T., & Li, G. et al. (2012). Orbital, charge, and spin couplings in Ru25+O9dimers of Ba3CoRu2O9. Physical Review B, 85(4). doi: 10.1103/physrevb.85.041201 NO This work is supported by NSF-DMR-0654118 and the State of Florida. J.S.B. and A.K. acknowledge support from NSF-DMR-1005293 DS Minerva RD 24 abr 2026