RT Journal Article
T1 Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process
A1 Fernández-Fariña, Sandra
A1 González Barcia, Luis
A1 Romero Castro, María José
A1 García Tojal, Javier
A1 Maneiro Maneiro, Marcelino
A1 Seco, José M.
A1 Zaragoza Vérez, Guillermo
A1 Martínez-Calvo, Miguel
A1 Pedrido Castiñeiras, Rosa
A1 González Noya, Ana María
K1 Silver
K1 Cluster helicate
K1 Desulfurization process
K1 Bisthiosemicarbazone
AB We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction
PB Royal Society of Chemistry
YR 2021
FD 2021-12-06
LK http://hdl.handle.net/10347/32379
UL http://hdl.handle.net/10347/32379
LA eng
NO Fernández-Fariña, S., González-Barcia, L. M., Romero, M. J., García-Tojal, J., Maneiro, M., Seco, J. M., ... & Pedrido, R. (2022). Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process. Inorganic Chemistry Frontiers, 9(3), 531-536.
NO The research leading to these results has received funding from the following FEDER cofunded-grants: from Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia, 2017 GRC GI-1682 (ED431C 2017/01), 2018 GRC GI-1584 (ED431C 2018/13), MetalBIO Network (ED431D 2017/ 01), Ministerio de Ciencia, Innovación y Universidades, METALBIO (CTQ2017-90802-REDT) and MultiMetDrugs (RED2018-102471-T).Inorg.
DS Minerva
RD 24 abr 2026