RT Journal Article
T1 Tandem Brønsted Acid Promoted and Nazarov Carbocyclizations of Enyneacetals to Hydroazulenones
A1 Escalante Escalante, Luz Elizabeth
A1 González Rodríguez, Carlos
A1 Varela Carrete, Jesús Ángel
A1 Saá Rodríguez, Carlos
K1 Brönsted-acid
K1 Carbocyclizations
K1 Enynes
K1 Hydroazulenone
K1 Nazarov cyclizations
AB A new and efficient metal-free entry to hydroazulenones is reported. Enyneacetals were easily converted into hydroazulene skeletons by tandem Brønsted-acidpromoted carbocyclizations followed by stereospecific Nazarov cyclizations. The versatility of this transformation also allowed assembly of interesting heteroaromatic tricyclic systems.
PB Wiley
SN 1433-7851
YR 2012
FD 2012
LK http://hdl.handle.net/10347/23340
UL http://hdl.handle.net/10347/23340
LA eng
NO Escalante, L., González-Rodríguez, C., Varela, J. A., Saá, C. (2012). Tandem Brønsted Acid Promoted and Nazarov Carbocyclizations of Enyneacetals to Hydroazulenones. Angew. Chem. Int. Ed., 51, 49, 12316-12320
NO NOTICE: This is the peer reviewed version of the following article:Escalante, L., González-Rodríguez, C., Varela, J. A., Saá, C. (2012). Tandem Brønsted Acid Promoted and Nazarov Carbocyclizations of Enyneacetals to Hydroazulenones. Angew. Chem. Int. Ed., 51, 49, 12316-12320. [doi: 10.1002/anie.201205823]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archiving.
NO We thank the MICINN [Projects CTQ2011-28258, Consolider Ingenio 2010 (CSD2007-00006)] and Xunta de Galicia (2007/XA084 and CN2011/054) for financial support. L. E. thanks Fundayacucho (Venezuela) and Xunta de Galicia for predoctoral grants and C. G.-R. thanks the MICINN for a Juan de la Cierva Contract (JCI-2011-09946)
DS Minerva
RD 22 abr 2026