RT Dissertation/Thesis
T1 Polycyclic Aromatic Hydrocarbons (PAHs) containing Biphenylene and Cyclooctatetraene Units
A1 Bello García, Jesús
K1 Catalisis
K1 Rutenio
K1 Cicloadición
K1 Cotinos
K1 HAPs
AB Polycyclic aromatic hydrocarbons (PAHs) are a family oforganic compounds presents around us from oil to interstellarspace, that can be considered as well-defined graphenefragments. Defective PAHs with non hexagonal rings haveemerge as improved scaffolds due to their ability to modify theproperties of their planar analogous. The synthesis of bothsystems generally requires regioselective rings fusions, wheremetal-catalysed annulations have become one of the mostattractive strategies.Throughout this PhD thesis, 1,3- cyclohexadiene nuclei,presents in dihydrobiphenylenes systems, will be exploredtowards annulated systems containing biphenylenes unitsthrough oxidative process. Moreover, synthesis and reactivity ofstrained alkynes species (COTynes) for the formation of PAHswith COT units will also be adressed.
YR 2024
FD 2024
LK http://hdl.handle.net/10347/33518
UL http://hdl.handle.net/10347/33518
LA eng
DS Minerva
RD 27 abr 2026