RT Journal Article
T1 Bifunctional Skipped Dienes through Cu/Pd-Catalyzed Allylboration of Alkynes with B2pin2 and Vinyl Epoxides
A1 Vázquez Galiñanes, Nuria
A1 Velo Heleno, Isabel
A1 Fañanás-Mastral, Martín
K1 Chemical reactions
K1 Ethers
K1 Hydrocarbons
K1 Inorganic carbon compounds
K1 Vinyl
AB A method for the use of vinyl epoxides in catalytic allylboration of alkynes is described. This transformation allows for the synthesis of bifunctional skipped dienes bearing both an allylic alcohol and an alkenylboronate from simple starting materials with high regio- and stereoselectivity. These two functionalities provide these products with highly versatile reactivity, as shown by their stereocontrolled conversion into cyclic boron compounds and polyenes.
PB ACS Publications
SN 1523-7060
YR 2022
FD 2022
LK http://hdl.handle.net/10347/29690
UL http://hdl.handle.net/10347/29690
LA eng
NO https://doi.org/10.1021/acs.orglett.2c03390
NO Financial support from AEI (PID2020-118237RB-I00), the European Research Council (863914), the Xunta de Galicia (Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03), and the European Regional Development Fund (ERDF) is gratefully acknowledged. N.V.-G. thanks AEI for an FPI Predoctoral Fellowship
DS Minerva
RD 23 abr 2026