RT Journal Article
T1 A Stimuli‐Responsive Macromolecular Gear: Interlocking Dynamic Helical Polymers with Foldamers
A1 Rodríguez Riego, Rafael
A1 Suárez Picado, Esteban
A1 Quiñoá Cabana, Emilio
A1 Riguera Vega, Ricardo
A1 Freire Iribarne, Félix Manuel
K1 Chirality
K1 Chiral teleinduction
K1 Foldamers
K1 Helical polymers
K1 Poly(phenylacetylene)s
AB Herein, macromolecular gears composed of helical poly(phenylacetylenes) (PPAs) bearing short oligopeptides as pendant groups are described, in which the two structural motifs (framework and substituents) are combined. These gears are obtained by polymerization of the acetylene groups introduced at the C‐terminus of short oligopeptides formed by achiral (Aib)n units (n=1–3) derivatized at the N‐terminus by a single enantiomer (R or S) of α‐methoxy‐α‐trifluoromethylphenylacetic acid (MTPA, Mosher's reagent). The chiral information of the MTPA is transmitted to the achiral Aib fragments and, through either chiral tele‐induction and/or chiral harvesting mechanisms, is further transferred to the polyene backbones, which adopt preferentially P or M helical senses. Moreover, these materials also show dynamic behavior and respond to the action of external stimuli by either inverting the P/M sense and/or modifying the elongation in fully reversible processes
PB Wiley
SN 1433-7851
YR 2020
FD 2020
LK http://hdl.handle.net/10347/23380
UL http://hdl.handle.net/10347/23380
LA eng
NO R. Rodríguez, E. Suárez-Picado, E. Quiñoá, R. Riguera, F. Freire, Angew. Chem. Int. Ed. 2020, 59, 8616
NO This is the peer reviewed version of the following article: R. Rodríguez, E. Suárez-Picado, E. Quiñoá, R. Riguera, F. Freire, Angew. Chem. Int. Ed. 2020, 59, 8616, which has been published in final form at https://doi.org/10.1002/anie.201915488. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions
NO Financial support from MINECO (CTQ2015‐70519‐P), Xunta de Galicia (ED431C 2018/30, Centro singular de investigación de Galicia accreditation 2019–2022, ED431G 2019/03 and the European Regional Development Fund (ERDF) is gratefully acknowledged. E.S.P. thanks MINECO for his FPU fellowship
DS Minerva
RD 24 abr 2026