RT Journal Article
T1 Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizations
A1 Varela Fernández, Alejandro
A1 Varela Carrete, Jesús Ángel
A1 Saá Rodríguez, Carlos
K1 Heterocyclizations
K1 Indoles
K1 Isoquinolines
K1 Quinolines
K1 Ruthenium
K1 Vinylidenes
AB Indoles, dihydroisoquinolines and dihydroquinolines were efficiently prepared by ruthenium-catalyzed heterocyclizations of aromatic homo- and bis-homopropargyl amines/amides in the presence of an amine/ammonium base-acid pair. These regioselective 5- and 6-endo cyclizations most probably occur by nucleophilic trapping of key Ru vinylidene intermediates.
PB Thieme
SN 0039-7881
YR 2012
FD 2012
LK http://hdl.handle.net/10347/23341
UL http://hdl.handle.net/10347/23341
LA eng
NO Varela-Fernández, A., Varela, J. A., Saá, C. (2012). Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizations. Synthesis, 44, 21, 3285-3295
NO NOTICE: This is the peer reviewed version of the following article: Varela-Fernández, A., Varela, J. A., Saá, C. (2012). Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizations. Synthesis, 44, 21, 3285-3295. [doi: 10.1055/s-0032-1316539]. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archiving
NO We thank the MICINN [Project CTQ2011-28258, Consolider Ingenio 2010 (CSD2007-00006)], Xunta de Galicia andEuropean Regional Development Fund (2007/XA084 and CN2011/054) for financial support. A. V.-F- thanks the USC for a predoctoral contract
DS Minerva
RD 30 abr 2026