RT Journal Article T1 Polycyclic aromatic hydrocarbons (PAHs) levels in PM10 and bulk deposition using Mosspheres: a pilot study in an urban environment A1 Pacín Salvador, María do Carme A1 Martínez Abaigar, Javier A1 Núñez Olivera, Encarnación A1 Aboal Viñas, Jesús A1 Nicola, Flavia de A1 Fernández Escribano, José Ángel K1 Polycyclic aromatic hydrocarbons K1 Passive air sampler K1 Air pollution K1 Moss K1 Biomonitoring K1 Mapping AB Study air polycyclic aromatic hydrocarbons (PAHs) capturing the spatial variability of their concentrations is not economically feasible with conventional methods. In the present work we tested, for the first time and under real conditions, the suitability for intensive monitoring and mapping these contaminants of innovative, cost-effective passive air samplers known as “Mosspheres”. The Mosspheres, filled with a devitalised Sphagnum palustre L. moss clone, were placed in a 575 m. grid in a medium-sized European city for three months. Concentrations in the moss tissues of 15 priority PAHs, including benzo(a)pyrene, were determined and converted into PM10 and bulk deposition with the equations proposed in a recent study. Low concentrations of PAHs were detected, with only a few enriched points never exceeding the legal thresholds, near industrial areas and busy roads. Despite these low PAH concentrations, Mosspheres were able to detect spatial structure for several PAHs and high-resolution pollution maps were constructed for these compounds. The results prove the high sensitivity and suitability of Mosspheres for mapping PAH levels and for quantitative (i.e. PAHs with 4 or more rings) and qualitative (3-ring PAHs) monitoring. Thus, this study supports their widespread application and its potential inclusion in European Directives on air quality control PB Elsevier SN 0013-9351 YR 2023 FD 2023 LK http://hdl.handle.net/10347/30321 UL http://hdl.handle.net/10347/30321 LA eng NO Environmental Research 223 (2023) 115406. https://doi.org/10.1016/j.envres.2023.115406 NO This work was financially supported by Caixabank, together with MCIN/AEI/10.13039/501100011033 and “ERDF A way of making Europe” (grant PGC2018-093824-B-C42). The Government of La Rioja (Dirección General de Calidad Ambiental) and the Council of Logroño provided administrative support for the study and the authorization to locate the sampling devices in the city. DS Minerva RD 24 abr 2026