RT Book,_Section
T1 On the Mechanism of Rhodium-Catalyzed [6+2] Cycloaddition of 2-Vinylcylobutanones and Alknenes
A1 Montero Campillo, María de la Merced
A1 Cabaleiro Lago, Enrique Manuel
A1 Rodríguez Otero, Jesús
AB The intramolecular [6+2] cycloaddition mechanism of 2­vinylcyclobutanones and  alkenes catalyzed by the [Rh(CO)2Cl]2 dimer has been studied using density functional theory,  comparing this multistep process with the one­step reaction in absence of catalyst. This possible  mechanism agrees with what was previously experimentally suggested. Calculations have also  allowed to explain the selectivity of the reaction
PB MDPI
SN 3-906980-19-7
YR 2007
FD 2007
LK http://hdl.handle.net/10347/26833
UL http://hdl.handle.net/10347/26833
LA eng
NO Montero­ Campillo, M.M.; Cabaleiro ­Lago, E.M.; Rodríguez ­Otero, J. On the Mechanism of Rhodium-Catalyzed [6+2] Cycloaddition of 2-Vinylcylobutanones and Alknenes, in Proceedings of the 11th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2007, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-11-01369
NO The 11th International Electronic Conference on Synthetic Organic Chemistry session Computational Chemistry
DS Minerva
RD 22 abr 2026