RT Journal Article
T1 3D printing of a palladium-alumina cermet monolithic catalyst: catalytic evaluation in microwave-assisted cross-coupling reactions
A1 Castro Tubío, José Manuel
A1 Malatini, Camilla
A1 Barrio Cagigal, Victoria Laura
A1 Fernández Masaguer, Jorge Christian
A1 Amorín López, Manuel
A1 Nabgan, ‪Walid
A1 Taboada Antelo, Pablo
A1 Gil González, Álvaro
A1 Coelho Cotón, Alberto José
K1 3D-printing
K1 Heterogeneous catalyst
K1 Palladium-cross-coupling reactions
K1 Microwave-assisted reactions
K1 Metal-ceramic
AB A straightforward manufacture strategy is proposed to obtain an efficient and robust palladium-alumina (Pd0/Al2O3) cermet monolithic catalyst, specifically designed to perform safe microwave assisted organic synthesis (MAOS). In this approach, a cermet catalyst with high surface area, controlled composition and adapted shape and dimensions to a microwave reactor vessel is generated via 3D printing technology and sintering. The resulting catalyst has been explored in heterogeneous Suzuki, Sonogashira, Stille and Heck cross-coupling reactions, in MAOS. The Pd0 catalyst is permanently active, stable, without leaching and can be recycled and reused at least 200 reaction cycles. The generation of hot spots, sparking or hazardous discharges is controlled by the effective immobilization of the palladium in the monolithic structure during the reaction. The palladium content is forming part of both the internal and external structure, providing greater mechanical resistance and catalytic activity with respect to the basic ceramic material (alumina)
PB Elsevier
YR 2022
FD 2022
LK http://hdl.handle.net/10347/29886
UL http://hdl.handle.net/10347/29886
LA eng
NO Materials Today Chemistry
NO This work was financially supported by the Consellería de Cultura, Educación e Ordenación Universitaria of the Galician Government: EM2014/022 to A.C., ED431B2016/028 to F.G. The Strategic Grouping AEMAT grant No. ED431E2018/08 and the Spanish Ministry of Science, Innovation and Universities with grant No: MAT2017-90100-C2-1-P "MA thanks Xunta de Galicia and the ERDF (ED431C 2021/21)"
DS Minerva
RD 23 abr 2026