RT Book,_Section
T1 H-Bonded Polymerisation of Alternate Δ and Λ Metallohelicates
A1 García Deibe, Ana María
A1 Portela García, 
A1 Portela García, Cristina
A1 Fondo Busto, María Matilde
A1 Sanmartín Matalobos, Jesús
K1 Chirality
K1 H-bond
K1 Polymer
K1 Metallohelicate
K1 Self-assembly
AB he neutral cadmium(II) complex Cd(HL)2 (H2L = 2-[(1H-imidazol-2-yl)methyleneamino]phenol) is chiral and it can be considered as a simple metallohelicate, with its corresponding Δ and Λ enantiomers. In the solid state, its helixes are hierarchically assembled as a linear polymer, via mutual N-H···O interactions between each two alternating enantiomers, and which also are π-π stacked, so this polymer is based on a by a dimeric repeat unit {Δ,Λ-[Cd(HL)2]2}
PB MDPI
SN 978-3-906980-55-3
YR 2015
FD 2015
LK http://hdl.handle.net/10347/25978
UL http://hdl.handle.net/10347/25978
LA eng
NO García-Deibe, A., Portela-García, C., Fondo, M. & Sanmartín-Matalobos, J. (2015). H-bonded polymerisation of alternate ∆ and Λ metallohelicates. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-18: The 18Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2014. MDPI. doi: 10.3390/ecsoc-18-d011
NO The 18th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistry
DS Minerva
RD 24 abr 2026