RT Journal Article
T1 The chelate−to−bridging shift of phosphane dipalladacycles:  convenient synthesis of double A‐frame tetranuclear complexes
A1 Frieiro Gomis, Pablo
A1 Lucio Martínez, Fátima
A1 Munín Cruz, Paula
A1 Ortigueira Amor, Juan Manuel
A1 Pereira Lorenzo, María Teresa
A1 Polo Ces, Paula
A1 Vázquez García, Digna
A1 Vila Abad, José Manuel
K1 Phosphane dipalladacycles
K1 Chelate-to-bridging
K1 Tetranuclear complexes
AB Palladacycles of the type [Pd2(Ph2PCH2PPh2-P,P)2(C,N:C,N)] (C,N:C,N = bis(N-2,3,4-trimethoxybenzylidene)-4,4′-sulfonyldianiline or -4,4′-oxydianiline) can undergo a spontaneous slow chelate-to-bridging diphosphane coordination shift in solution. Following this strategy a tailor-made synthetic procedure was devised that culminates in isolation of double A-frame tetranuclear palladium complexes.
PB Royal Society of Chemistry
SN 1359-7345
YR 2018
FD 2018-02-19
LK https://hdl.handle.net/10347/39367
UL https://hdl.handle.net/10347/39367
LA eng
NO Frieiro-Gomis, P., Lucio-Martínez, F., Munín-Cruz, P., M. Ortigueira, J., Teresa Pereira, M., Polo-Ces, P., Vázquez-García, D., & M. Vila, J. (2018). The chelate-to-bridging shift of phosphane dipalladacycles: Convenient synthesis of double A-frame tetranuclear complexes. “Chemical Communications”, 54(21), 2662-2665. https://doi.org/10.1039/C8CC01046C
DS Minerva
RD 23 abr 2026