RT Journal Article
T1 Sorption and Desorption of Vanadate, Arsenate and Chromate by Two Volcanic Soils of Equatorial Africa
A1 González Rodríguez, Sara
A1 Fernández Marcos, María Luisa
K1 Andosol
K1 Silandic Andosol
K1 Vitric Andosol
K1 Andosols
K1 Oxyanions
K1 Potentially toxic elements
K1 Rwanda
K1 São Tomé and Príncipe
K1 Freundlich isotherm
K1 Temkin isotherm
AB Sorption of oxyanions by soils and mineral surfaces is of interest due to their role as nutrients or pollutants. Volcanic soils are variable charge soils, rich in active forms of aluminum and iron, and capable of sorbing anions. Sorption and desorption of vanadate, arsenate, and chromate by two African andosols was studied in laboratory experiments. Sorption isotherms were determined by equilibrating at 293 K soil samples with oxyanion solutions of concentrations between 0 and 100 mg L−1 V, As, or Cr, equivalent to 0−2.0 mmol V L−1, 0−1.3 mmol As L−1, and 0−1.9 mmol Cr L−1, in NaNO3; V, As, or Cr were determined by ICP-mass spectrometry in the equilibrium solution. After sorption, the soil samples were equilibrated with 0.02 M NaNO3 to study desorption. The isotherms were adjusted to mathematical models. After desorption with NaNO3, desorption experiments were carried out with a 1 mM phosphate. The sorption of vanadate and arsenate was greater than 90% of the amount added, while the chromate sorption was much lower (19–97%). The sorption by the Silandic Andosol is attributed to non-crystalline Fe and Al, while in the Vitric Andosol, crystalline iron species play a relevant role. The V and Cr sorption isotherms fitted to the Freundlich model, while the As sorption isotherms conformed to the Temkin model. For the highest concentrations of oxyanions in the equilibrating solution, the sorbed concentrations were 37–38 mmol V kg−1, 25 mmol As kg−1, and 7.2–8.8 mmol Cr kg−1. The desorption was low for V and As and high for Cr. The comparison of the sorption and desorption isotherms reveals a pronounced hysteresis for V in both andosols and for Cr in the Silandic Andosol. Phosphate induced almost no V desorption, moderate As desorption, and considerable Cr desorption
PB MDPI
YR 2021
FD 2021
LK http://hdl.handle.net/10347/25267
UL http://hdl.handle.net/10347/25267
LA eng
NO Gonzalez-Rodriguez, S.; Fernandez-Marcos, M.L. Sorption and Desorption of Vanadate, Arsenate and Chromate by Two Volcanic Soils of Equatorial Africa. Soil Syst. 2021, 5(2), 22; https://doi.org/10.3390/soilsystems5020022
DS Minerva
RD 24 abr 2026