RT Journal Article T1 Chiral information harvesting in helical poly(acetylene) derivatives using oligo(p-phenyleneethynylene)s as spacers A1 Fernández Villar, Zulema A1 Fernández Rodríguez, Berta A1 Quiñoá Cabana, Emilio A1 Riguera Vega, Ricardo A1 Freire Iribarne, Félix Manuel AB A chiral harvesting transmission mechanism is described in poly(acetylene)s bearing oligo(p-phenyleneethynylene)s (OPEs) used as rigid achiral spacers and derivatized with chiral pendant groups. The chiral moieties induce a positive or negative tilting degree in the stacking of OPE units along the polymer structure, which is further harvested by the polyene backbone adopting either a P or M helix PB Royal Society of Chemistry YR 2020 FD 2020 LK http://hdl.handle.net/10347/23374 UL http://hdl.handle.net/10347/23374 LA eng NO Chem. Sci., 2020, 11, 7182 DS Minerva RD 28 abr 2026