RT Journal Article
T1 Copper-catalyzed O-alkenylation of phosphonates
A1 Vázquez Galiñanes, Nuria
A1 Andón Rodríguez, Mariña
A1 Gómez Roibás, Patricia
A1 Fañanás-Mastral, Martín
K1 Alkenylation
K1 Copper
K1 C(sp2)–O Bond Formation
K1 Hypervalent Iodine
K1 Phosphonates
AB Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phosphonates in very good yields.
PB Beilstein Institute
YR 2020
FD 2020
LK http://hdl.handle.net/10347/21780
UL http://hdl.handle.net/10347/21780
LA eng
NO Vázquez-Galiñanes, N.; Andón-Rodríguez, M.; Gómez-Roibás, P.; Fañanás-Mastral, M. Beilstein J. Org. Chem. 2020, 16, 611–615. doi:10.3762/bjoc.16.56
NO Financial support from the AEI (CTQ2017-88451-R), Xunta de Galicia (ED431F 2016/006; ED431C 2018/04; Centro singular de investigación de Galicia accreditation 2016-2019, ED431G/09) and the European Union (ERDF) is gratefully acknowledged. N. V.-G. thanks AEI for a predoctoral FPI fellowship.
DS Minerva
RD 24 abr 2026