RT Journal Article
T1 Poly(phenylacetylene) Amines: A General Route to Water-Soluble Helical Polyamines
A1 Suárez Picado, Esteban
A1 Quiñoá Cabana, Emilio
A1 Riguera Vega, Ricardo
A1 Freire Iribarne, Félix Manuel
AB Polyphenylacetylenes bearing prim- and secaminegroups are barely known due to their poisoningactivity towards the polymerization catalyst. Herein weprepare 11 different amino polymers in high yields bydirect polymerization of their corresponding ammoniumsalts in water using [Rh(cod)2] +BF4- as catalyst. They arestable, water soluble, and show a helical structure thatresponds to external stimuli (polarity, pH and metalions) acting on the pendants. The location of the aminogroup in the pendant is shown to be critical for the helicalresponse to protonation
PB American Chemical Society
SN 0897-4756
YR 2018
FD 2018-09-12
LK http://hdl.handle.net/10347/18880
UL http://hdl.handle.net/10347/18880
LA eng
NO Suárez-Picado, E., Quiñoá, E., Riguera, R., & Freire, F. (2018). Poly(phenylacetylene) Amines: A General Route to Water-Soluble Helical Polyamines. Chemistry Of Materials, 30(19), 6908-6914. doi: 10.1021/acs.chemmater.8b03238
NO This is the Accepted Manuscript version of a Published Work that appeared in final form in Chemistry of Materials, Copyright © 2018 American Chemical Society after peer review and technical edityng by the publisher. To access the final edited and published work see: https://pubs.acs.org/doi/10.1021/acs.chemmater.8b03238
NO Financial support from MINECO (CTQ2014-61470-EXP,CTQ2015-70519-P), Xunta de Galicia (GRC2014/040, Centrosingular de investigación de Galicia accreditation 2016-2019, ED431G/09) and the European Regional DevelopmentFund (ERDF) is gratefully acknowledged. E. S. P. isgrateful to MINECO for a FPU predoctoral fellowship
DS Minerva
RD 23 abr 2026