RT Journal Article
T1 GC-MS screening for the identification of potential migrants present in polymeric coatings of food cans
A1 Lestido Cardama, Antía
A1 Sendón García, Raquel
A1 Bustos, Juana
A1 Santillana, M. Isabel
A1 Paseiro Losada, Perfecto
A1 Rodríguez Bernaldo de Quirós, Ana Isabel
K1 Screening
K1 GC-MS
K1 LC-MS/MS
K1 BADGE
K1 Cans
K1 Cyclo-di-BADGE
AB The coatings used in cans can release complex chemical mixtures into foodstuffs. Therefore, it is important to develop analytical methods for the identification of these potential migrant compounds in packaged food to guarantee the compliance with European food packaging legislation and ensure consumer safety. In the present work, the type of coating in a total of twelve cans collected in Santiago de Compostela (Spain) were evaluated using an ATR (attenuated total reflectance)-FTIR spectrometer. These samples were analysed after extraction with acetonitrile in order to identify potential migrants through a screening method by gas chromatography coupled to mass spectrometry (GC-MS). A total of forty-seven volatile and semi-volatile compounds were identified in these samples, including plasticizers, photoinitiators, antioxidants, lubricants, etc. Then, in a second step, a targeted analysis was carried out for the simultaneous determination of 13 compounds, including bisphenols (BPA, BPB, BPC, BPE, BPF, BPG) and BADGEs (BADGE, BADGE.H2O, BADGE.2H2O, BADGE.HCl, BADGE.2HCl, BADGE.H2O.HCl, cyclo-di-BADGE) by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) with atmospheric pressure chemical ionisation (APCI) source. Among all the bisphenols analysed, only the bisphenol A was detected in four samples; while cyclo-di-BADGE was the predominant compound detected in all the samples analysed.
PB MDPI
YR 2019
FD 2019
LK http://hdl.handle.net/10347/21054
UL http://hdl.handle.net/10347/21054
LA eng
NO Lestido Cardama, A.; Sendón, R.; Bustos, J.; Santillana, M.I.; Paseiro Losada, P.; Rodríguez Bernaldo de Quirós, A. GC-MS Screening for the Identification of Potential Migrants Present in Polymeric Coatings of Food Cans. Polymers 2019, 11, 2086
NO This research was funded by the Ministerio de Ciencia, Innovación y Universidades, by Fondo Europeo de Desarrollo Regional (FEDER), and by Agencia Estatal de Investigación Ref.No. PGC2018-094518-B-I00 “MIGRACOATING” (MINECO/FEDER, UE)
DS Minerva
RD 22 abr 2026