RT Journal Article T1 On the physical foundations of topological thermoelectricity and its improvement A1 Baldomir Fernández, Daniel A1 Failde, Daniel K1 Thermoelectricity K1 Topological materials AB Thermoelectricity has extraordinary scientific and technological interest due to its ability to utilize heat losses through the Seebeck effect and Peltier cooling in circuits. However, the efficiency of thermoelectric materials remains relatively low, making them economically viable in fewer cases than desired. A promising possibility lies in the best thermoelectric materials at room temperature, specifically the well-known tetradymite-type structures, primarily compounds based on . These materials are characterized as topological insulators, allowing for the introduction of new physical perspectives. Therefore, it is reasonable to closely investigate the interplay between topology and thermoelectricity in these systems, with the aim of elucidating the underlying physical mechanisms. We show that, near the surface–bulk interface, the electrodynamics of axions coupled to massless fermions, Thouless pump currents, the chiral anomaly, and topological mass are intimately interconnected in a way that enables the mutual conversion of heat and electrical energy. That gives rise to a thermoelectric effect whose efficiency can be enhanced by integer multiples. We extend this study to heterostructures of topological insulators and topological superconductors. These phases are topologically complementary and may use the proximity effect to share topological quantum numbers. This offers a pathway to enhance topological thermoelectricity. PB Elsevier SN 0370-1573 YR 2026 FD 2026-01-22 LK https://hdl.handle.net/10347/46966 UL https://hdl.handle.net/10347/46966 LA eng NO Baldomir, D., & Failde, D. (2026). On the physical foundations of topological thermoelectricity and its improvement. Physics Reports, 1154, 1–48. 10.1016/j.physrep.2025.10.004 NO D.B was supported by the project PID2022-138883NB-I00 funded by the Spanish Ministry of Science, Innovation and Universities, and by the European Union project MiniStor (H2020 GA No 869821). D.F was supported by MICIN through the European Union NextGenerationEU recovery plan (PRTR-C17.I1), and by the Galician Regional Government through the “Planes Complementarios de I+D+I con las Comunidades Autónomas” in Quantum Communication. DS Minerva RD 24 may 2026