RT Journal Article
T1 Rhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes
A1 Araya, Marisel
A1 Gulías Costa, Moisés
A1 Fernández, Israel
A1 Bhargava, Gaurav
A1 Castedo Expósito, José Luis
A1 Mascareñas Cid, José Luis
A1 López García, Fernando
K1 Alkylidenecyclopropane
K1 Carbocycles
K1 Catalysis
K1 Cycloadditions
K1 Rhodium
AB A Rh-catalyzed intramolecular [3+2+2] cycloaddition is reported. The cycloaddition affords synthetically relevant 5,7,5-fused tricyclic systems of type 2 from readily available dienyne precursors. The transformation takes place with moderate or good yields, high diastereoselectivity, and total chemoselectivity
PB WILEY-VCH Verlag GmbH
SN 1521-3765
YR 2014
FD 2014-07-17
LK http://hdl.handle.net/10347/11966
UL http://hdl.handle.net/10347/11966
LA eng
NO Araya, M., Gulías, M., Fernández, I., Bhargava, G., Castedo, L., Mascareñas, J. L. and López, F. (2014), Rhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes. Chem. Eur. J., 20: 10255–10259. doi: 10.1002/chem.201402473
NO Spanish MINECO. Grant Numbers: SAF2010-20822-C02-01/02, CTQ2010-20714-C02-01/BQU, CSD2007-00006ERDFXunta de Galicia. Grant Numbers: GRC2010/12, GR2013-041, INCITE09 209084PR, EM2013/036European Research Council. Grant Number: 340055CAM. Grant Number: S2009/PPQ-1634, AVANCAT
DS Minerva
RD 24 abr 2026