RT Journal Article
T1 Simultaneous Adjustment of Size and Helical Sense of Chiral Nanospheres and Nanotubes Derived from Axially Racemic Poly(phenyl acetylene)s
A1 Arias, Sandra
A1 Núñez Martínez, Manuel
A1 Quiñoá Cabana, Emilio
A1 Riguera Vega, Ricardo
A1 Freire Iribarne, Félix Manuel
K1 Nanospheres
K1 Nanotubes
K1 Helices
K1 Poly(phenylacetylene)s
K1 Helical sense
AB Nanospheres and nanotubes with full control of their size and helical sense are obtained in chloroform from the axially racemic chiral poly(phenylacetylene) poly-(R)-1 using either Ag+ as both chiral inducer and cross-linking agent or Na+ as chiral inducer and Ag+ as cross-linking agent. The size is tuned by the polymer/ion ratio while the helical sense is modulated by the polymer/cosolvent (i.e., MeCN) ratio. In this way, the helicity and the size of the nanoparticles can be easily interconverted by very simple experimental changes
PB Wiley
YR 2016
FD 2016-10-19
LK http://hdl.handle.net/10347/16405
UL http://hdl.handle.net/10347/16405
LA eng
NO S. Arias, M. Núñez-Martínez, E. Quiñoá, R. Riguera, F. Freire, Small 2017, 13, 1602398
NO MEC. Grant Numbers: CTQ2014-61470-EXP, CTQ2015-70519-P Xunta de Galicia. Grant Numbers: GRC2014/040, EM2013/0032
DS Minerva
RD 28 abr 2026