RT Journal Article
T1 Oxidation of Alkynes via Catalytic Metal-Vinylidenes
A1 Álvarez Pérez, Andrea
A1 Saá Rodríguez, Carlos
A1 Varela Carrete, Jesús Ángel
K1 Amides
K1 Cyclization
K1 Esters
K1 β-Lactams
K1 Ketenes
K1 Vinylidenes
AB Metal-vinylidenes, generated by treatment of terminal alkynes with transition metals, are very useful intermediates in modern synthetic chemistry as shown by the high number of transformations in which they are involved. When a metal-vinylidene is generated in the presence of an oxidant, its immediate oxidation to a ketene intermediate occurred. In this short review, recent synthetic applications of the oxidation of alkynes via ketene intermediates from initially formed metal-vinylidenes are highlighted.
PB Thieme
SN 0039-7881
YR 2020
FD 2020
LK http://hdl.handle.net/10347/23361
UL http://hdl.handle.net/10347/23361
LA eng
NO Álvarez-Pérez, A., Saá, C., Varela, J. A. (2020). Oxidation of Alkynes via Catalytic Metal-Vinylidenes. Synthesis, 52, 18, 2639-2649
NO NOTICE: This is the peer reviewed version of the following article: Álvarez-Pérez, A., Saá, C., Varela, J. A. (2020). Oxidation of Alkynes via Catalytic Metal-Vinylidenes. Synthesis, 52, 18, 2639-2649. [doi: 10.1055/s-0040-1707860]. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archiving
NO This work has received financial support from MINECO (project CTQ2017-87939R and ORFEO-CINQA network RED2018-102387-T), the Xunta de Galicia (project ED431C 2018/04 and Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03) and the European Union (European Regional Development Fund – ERDF)
DS Minerva
RD 28 abr 2026