RT Journal Article
T1 Cobalt-Catalyzed (3 + 2) Cycloaddition of Cyclopropene-Tethered Alkynes: Versatile Access to Bicyclic Cyclopentadienyl Systems and Their CpM Complexes
A1 Lázaro-Milla, Carlos
A1 Concepcion, Eduardo da
A1 Fernández, Israel
A1 Mascareñas Cid, José Luis
A1 López García, Fernando José
K1 Cyclopropene
K1 Cycloaddition
K1 Cobalt
K1 Catalysis
K1 Cyclopentadienes
K1 CpM catalysts
AB Low-valent cobalt complexes can promote intramolecular (3 + 2) cycloadditions of alkyne-tethered cyclopropenes to provide bicyclic systems containing highly substituted cyclopentadienyl moieties with electronically diverse functional groups. The adducts can be easily transformed into new types of CpRh(III) and CpIr(III) complexes, which show catalytic activity in several relevant transformations. Preliminary computational (DFT) and experimental studies provide relevant information on the mechanistic peculiarities of the cobalt-catalyzed process and allow us to rationalize its advantages over the homologous rhodium-promoted reaction.
PB American Chemical Society
YR 2024
FD 2024
LK https://hdl.handle.net/10347/37629
UL https://hdl.handle.net/10347/37629
LA eng
NO ACS Catal. 2024, 14, 15, 11574–11583
NO This work received financial support from Spanish grants (Grants PID2020-118579GB-I00, PID2019-108624RB-I00 and PID2022-139318NB-I00 funded by MCIN/AEI/10.13039/501100011033, ORFEO–CINQA network RED2022-134287-T), the Consellería de Cultura, Educación e Ordenación Universitaria (Grant ED431C 2021/25 and Grant ED431G 2019/03: Centro Singular de Investigación de Galicia accreditation 2023-2027, ED431G 2023/03, and predoctoral grant to EdC) and the European Union (European Regional Development Fund-ERDF corresponding to the multiannual financial framework 2014-2020)
DS Minerva
RD 24 abr 2026