RT Journal Article
T1 Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes
A1 Chaves Pouso, Andrea
A1 Rivera Chao, Eva
A1 Fañanás-Mastral, Martín
AB A copper-catalyzed protoboration of borylated dendralenes is reported. The method employs an NHC–Cu catalyst and provides access to 1,4-addition products with excellent levels of chemo-, regio- and stereoselectivity. The resulting diene bis(boronates) are oxidized to the corresponding diene diols which are synthetically versatile building blocks.
PB Royal Society of Chemistry
YR 2020
FD 2020
LK http://hdl.handle.net/10347/23373
UL http://hdl.handle.net/10347/23373
LA eng
NO Chaves-Pouso, A., Rivera-Chao, E., & Fañanás-Mastral, M. (2020). Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes. Chemical Communications. https://doi.org/10.1039/d0cc04018e
NO Financial support from the AEI (CTQ2017-88451-R), Xunta de Galicia (ED431C 2018/04; Centro singular de investigación de Galicia accreditation 2019–2022, ED431G 2019/03) and the European Union (European Regional Development Fund – ERDF) is gratefully acknowledged. E. R.-C. thanks Xunta de Galicia for predoctoral fellowship
DS Minerva
RD 24 abr 2026