RT Journal Article
T1 Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review
A1 Corredoira Vázquez, Julio
A1 González-Barreira, Cristina
A1 Oreiro-Martínez, Paula
A1 García Deibe, Ana María
A1 Sanmartín Matalobos, Jesús
A1 Fondo Busto, María Matilde
K1 Lanthanoid
K1 N5, N6 macrocycle
K1 Coordination chemistry
K1 Chirality
K1 Biological activity
K1 Molecule magnet
AB In this paper, the lanthanoid complexes of N5 and N6 macrocycle ligands, without pendant arms or additional heteroatoms, are surveyed. This review covers the period from 2015 to the current date, since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety, and their complexes, were revised, and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also summarized. Porphyrin and phthalocyanine ligands are not included in this review, which primarily focuses on complexes with Schiff bases and amines without pendant arms or any additional donor other than nitrogen. The synthetic methods, structural characterization, based on single X-ray crystal data, and properties of the lanthanoid complexes, with special attention to magneto-structural correlations, are presented herein.
PB Elsevier
SN 1002-0721
YR 2024
FD 2024-01
LK http://hdl.handle.net/10347/32219
UL http://hdl.handle.net/10347/32219
LA eng
NO Corredoira Vázquez, J., González Barreira, C., Oreiro Martínez, P., García Deibe, A.M., Sanmartín Matalobos, J., Fondo, M., (2024), Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: A review. "Journal of Rare Earths", vol.42, 1-15
NO J.C-V acknowledges Xunta de Galicia for his postdoctoral fellowship (ED481B-2022-068). P.O-M. thanks the Fundación Segundo Gil Davila for her PhD fellowship.
DS Minerva
RD 22 abr 2026