RT Journal Article T1 Composite Films with UV-Barrier Properties Based on Bacterial Cellulose Combined with Chitosan and Poly(vinyl alcohol): Study of Puncture and Water Interaction Properties A1 Cazón Díaz, Patricia A1 Vázquez Vázquez, Manuel A1 Velázquez, Gonzalo K1 Biopolymers K1 Cellulose Optical properties Polymers Solubility K1 Cellulose K1 Optical properties K1 Polymers K1 Solubility AB The present study describes the preparation and characterization of composite films from bacterial cellulose produced by Komagataeibacter xylinus combined with poly(vinyl alcohol) and chitosan. The unique bacterial cellulose structure provides an expanded surface area with high porosity, easing the combination with other soluble polymers by dipping. This blending method effectively reinforces the bacterial cellulose structure. Toughness, puncture strength, water solubility, and swelling degree were measured to assess the effect of poly(vinyl alcohol) and chitosan on the analyzed properties. The morphology and optical and thermal properties were evaluated by scanning electron microscopy, UV–vis spectral analysis, thermogravimetry, and differential scanning calorimetry, respectively. Results showed that the films have good UV-barrier properties and high thermal stability. Toughness values ranged from 0.26 to 7.18 MJ/m3, burst strength ranged from 58.88 to 3234.62 g, and distance to burst ranged from 0.39 to 3.24 mm. Poly(vinyl alcohol) affected the water solubility and increased the swelling degree. PB ACS Publications SN 1525-7797 YR 2019 FD 2019-03-29 LK https://hdl.handle.net/10347/38514 UL https://hdl.handle.net/10347/38514 LA eng NO Cazón, P., Vázquez, M. and Velazquez, G. (2019) ‘Composite films with UV-barrier properties based on bacterial cellulose combined with chitosan and poly(vinyl alcohol): Study of puncture and water interaction properties’, Biomacromolecules, 20(5), pp. 2084–2095. doi:10.1021/acs.biomac.9b00317. NO This document is the Accepted Manuscript version of a Published Work that appeared in final form in Biomacromolecules, copyright © 2019 American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.biomac.9b00317 NO A grant from CONACYT (Mexico) to P.C. (no. 435948) is gratefully acknowledged. The financial support for this project was provided by Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia (ES) (project no. ED431B 2016/009). We acknowledge the use of RIAIDT-USC analytical facilities. DS Minerva RD 28 abr 2026