RT Journal Article
T1 Hydrolysis of a carbamate triggered by coordination of metal ions
A1 Fernández-Fariña, Sandra
A1 Martínez-Calvo, Miguel
A1 Romero Castro, María José
A1 Seco, José M.
A1 Zaragoza Vérez, Guillermo
A1 Pedrido Castiñeiras, Rosa
A1 González Noya, Ana María
K1 Hydrolysis
K1 Metal ions
K1 Carbamate
AB The mechanism of carbamate activation promoted by different metal ions has been explored in this work. The reaction of the carbamate ligand H2L with chloride metal salts (M = Ni, Cu, Zn, Cd) leads to the coordination of the metal ions to the ligand, causing hydrolysis of the systems. This self-immolation process results in mononuclear dihydrazone complexes, carbon dioxide and the release of alcohol species from the pendant groups of the carbamate ligand. The conditions under which this process occurs have been studied in detail.
PB Royal Society of Chemistry
YR 2022
FD 2022-07-28
LK http://hdl.handle.net/10347/32377
UL http://hdl.handle.net/10347/32377
LA eng
NO Fernández-Fariña, S., Martínez-Calvo, M., Romero, M. J., Seco, J. M., Zaragoza, G., Pedrido, R., & González-Noya, A. M. (2022). Hydrolysis of a carbamate triggered by coordination of metal ions. Dalton Transactions, 51(34), 12915-12920.
NO The research leading to these results has received funding from the following FEDER cofounded-grants. From Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia, 2017GRCGI-1682 (ED431C2017/01), 2018GRCGI-1584 (ED431C2018/13), MetalBIONetwork (ED431D2017/01). From Ministerio de Ciencia, Innovación y Universidades, METALBIO (CTQ2017-90802-REDT). From Ministerio de Ciencia e Innovación (MCIN), MultiMetDRUGS (RED2018-102471-T) and Project PID2021-127531NB-I00 (AEI/10.13039/501100011033/ FEDER, UE).
DS Minerva
RD 23 abr 2026