RT Journal Article T1 Cracks in consolidants containing TiO2 as a habitat for biological colonization: A case of quaternary bioreceptivity A1 Sanmartín Sánchez, Patricia A1 Noya Pintos, Daniel A1 Fuentes Alonso, Elsa A1 Pozo Antonio, José Santiago K1 Biodeterioration K1 Greening K1 Consolidant K1 Stone K1 Nanotechnology K1 TiO2 AB The recently proposed concept of quaternary bioreceptivity applies to substrates treated with coating materials and it is considered in the present study with the alga Bracteacoccus minor and the cyanobacterium Nostoc sp. onto granite specimens treated with ethyl silicate and nano-sized silica doped with different amounts of TiO2 (0, 0.5, 1 and 3 wt%). The findings showed a lack of correlation between the amount of TiO2 and the level of colonization (main bioreceptivity estimator) to the presence of cracks on the surface, which annul the biocidal power of TiO2. Crack formation, which depends on the mechanical properties, greatly influences the bioreceptivity of the material. Thus, the cracks provided anchor points where water is retained, in turn strongly influencing the early stages of colonization kinetics, to a greater extent than the biocidal power of TiO2, which will probably increase as the biofilm develops over the entire surface. In addition, although the cracks were more abundant and wider in the ethyl silicate-based consolidant, the nano-sized silica provided better anchoring points, making the material treated with the corresponding consolidant more bioreceptive PB Elsevier YR 2021 FD 2021 LK http://hdl.handle.net/10347/27521 UL http://hdl.handle.net/10347/27521 LA eng NO Materials Science and Engineering: C 124 (2021) 112058 DS Minerva RD 29 abr 2026