RT Journal Article T1 Removal of pigments from aqueous solution by a calcium alginate–grape marc biopolymer: A kinetic study A1 Pérez-Ameneiro, María A1 Vecino, Xanel A1 Barbosa Pereira, Letricia A1 Cruz, J. M. A1 Moldes, Ana B. K1 Grape marc K1 Adsorption K1 Biopolymer K1 Kinetics K1 Dyes AB In this work, the potential use of a biopolymer based on grape marc entrapped in calcium alginate beads for the removal of pigments from an agro industrial effluent was evaluated. The parameters that affect the pigment adsorption such as pH (3.5–7.0), temperature (10–40 °C) and initial pigment concentration (6.9–55.1 mg/L) were studied by applying an incomplete factorial design. The dependent variables evaluated consisted of color effluent parameters from CIELAB and Tristimulus system, as well as the concentration of pigments in the wastewater after the adsorption treatment. The most significant independent variables tested were the pigments concentration followed by pH, whereas temperature had a negligible effect on the adsorption process. Moreover, at the optimal operational conditions (pH 3.5 and room temperature) kinetic studies were carried out by applying pseudo-first order, pseudo-second order, Chien–Clayton and intraparticle diffusion models, observing a good agreement between theoretical and experimental results. PB Elsevier SN 0144-8617 YR 2014 FD 2014 LK https://hdl.handle.net/10347/39393 UL https://hdl.handle.net/10347/39393 LA eng NO Perez-Ameneiro, M., Vecino, X., Barbosa-Pereira, L., Cruz, J. M., & Moldes, A. B. (2014). Removal of pigments from aqueous solution by a calcium alginate–grape marc biopolymer: A kinetic study. Carbohydrate Polymers, 101, 954–960. https://doi.org/10.1016/j.carbpol.2013.09.091 NO Xunta de Galicia (project GPC, ref. 450 CN2012/277). DS Minerva RD 24 abr 2026