RT Journal Article
T1 Straightforward Synthesis of Novel Acene-Based Aryne Precursors
A1 Rodríguez-Lojo, Diego
A1 Peña Gil, Diego
A1 Pérez Meirás, María Dolores
A1 Guitián Rivera, Enrique
K1 Arynes
K1 Polycyclic aromatic hydrocarbons
K1 Acenes
K1 Diels–Alder reaction
K1 Cycloadditions
AB Large polycyclic o-(trimethylsilyl)aryl triflates are easily obtained by reaction of commercially available bisaryne precursors with cyclopentadienones. The transformation involves controlled generation of one of the aryne functionalities, trapping by Diels–Alder reaction with a dienone, and chelotropic extrusion of CO. The newly synthesized triflates are precursors of acene-based arynes, including a didehydropentacene
PB Thieme Publishing
SN 0936-5214
YR 2015
FD 2015-06-11
LK http://hdl.handle.net/10347/16988
UL http://hdl.handle.net/10347/16988
LA eng
NO Peña, D., Pérez, D., Rodríguez-Lojo, D., & Guitián, E. (2015). Straightforward Synthesis of Novel Acene-Based Aryne Precursors. Synlett, 26(11), 1633-1637. doi: 10.1055/s-0034-1381005
NO Financial support from the Spanish Ministry of Science and Competitiveness (MINECO, CTQ2013-44142-P and MAT2013-46593-C6-6-P), the European Union (Project PAMS, contract no. 610446), Xunta de Galicia (GPC2014/25), and FEDER is gratefully acknowledged. D.R.-L. thanks the Spanish Ministry of Education for the award of an FPU fellowship
DS Minerva
RD 24 abr 2026