RT Journal Article
T1 Cobalt-Catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes
A1 Da Concepción, Eduardo
A1 Fernández, Israel
A1 Mascareñas Cid, José Luis
A1 López García, Fernando
K1 Cobalt
K1 Alkylidenecyclopropane
K1 Cycloaddition
K1 Allene
K1 Diene
AB Low-valent cobalt complexes equipped with phosphorous type of ligands can promote the intramolecular (3+2) cycloaddition of alkylidenecyclopropanes (ACPs) with alkenes and with allenes. Dienes can also be used as partners, but they afford seven-membered cycloadducts. The reactions are fully diastereoselective and, in some cases, we also observed moderate enantioselectivities, especially when using chiral phosphite ligands.
PB Wiley
YR 2023
FD 2023
LK http://hdl.handle.net/10347/32851
UL http://hdl.handle.net/10347/32851
LA eng
NO Advanced Synthesis & Catalysis (ASC).
NO This work received financial support from Spanish grants (Grants PID2020-118579GB−I00 and PID2019-108624RB−I00 funded by MCIN/AEI/10.13039/501100011033, ORFEO-CINQA network RED2022-134287-T), the Consellería de Cultura, Educación e Ordenación Universitaria (Grant ED431C 2021/25 and Grant ED431G 2019/03: Centro Singular de Investigación de Galicia accreditation 2019–2022, and predoctoral grant to EdC) and the European Union (European Regional Development Fund-ERDF corresponding to the multiannual financial framework 2014–2020).
DS Minerva
RD 29 abr 2026