RT Dissertation/Thesis
T1 Poly(diphenylacetylene)s: Design, Synthesis and Application
A1 Tarrío Cordeiro, Juan José
K1 Helical Polymers
K1 Poly(diphenylacetylene)s
K1 Secondary Structure
K1 CPL materials
AB This Doctoral Thesis is focused on the development of new chiral materials based on poly(diphenylacetylene)s (PDPA). PDPAs are a family of helical polymers generally described as very stable and static, where the secondary structure —helical sense and/or elongation— cannot be modulated by external stimuli. Therefore, in this work we have explored different approaches to synthesize the first reported dynamic PDPAs, which has allowed us to create new stimuli-responsive materials. In addition, we have also focused on the elucidation of the secondary structure of those polymers to understand their structure-function relationship. These results can help the future rational design of novel smart materials with specific properties.
YR 2022
FD 2022
LK http://hdl.handle.net/10347/29436
UL http://hdl.handle.net/10347/29436
LA eng
DS Minerva
RD 22 abr 2026